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文獻名：Reversible Addition?Fragmentation Chain-Transfer Polymerization of Amphiphilic Polycarboxybetaines and Their Molecular Interactions
作者：Munziya Abutalip†‡, Anam Mahmood†, Raikhan Rakhmetullayeva ‡, Alexey Shakhvorostov¶♀Yerbol Dauletov, Sarkyt Kudaibergenov¶♀, and Nurxat Nuraje†
†Department of Chemical Engineering, Texas Tech University, Lubbock, Texas 79409
‡Department of Chemistry and Chemical Technology, al-Farabi Kazakh National University,
Almaty, Kazakhstan
¶Laboratory of Engineering Profile, K.I. Satpayev Kazakh National Research Technical
University, Almaty, Kazakhstan
♀Institute of Polymer Materials and Technology, Almaty, Kazakhstan
摘要：In this work, we report the first molecular weight-controlled amphiphilic polybetaine synthesis using various hydrocarbons via reversible addition?fragmentation chain-transfer (RAFT) polymerization. The experimental separation of the alkyl aminocrotonate tautomers, which has been the subject of debate, was completed for the first time. The enamine form of these tautomers was further used as a monomer for the RAFT polymerization of amphiphilic polycarboxybetaines. Self-assembly of the amphiphilic polycarboxybetaines showed micelle structures from spherical, rod-like to fractal in the aqueous media due to the competition between both electrostatic and hydrophobic forces. Hydrophobically dominant interactions among amphiphilic polycarboxybetaines and long-chain hydrocarbon alkane molecules were investigated to understand long-chain hydrocarbon alkane crystallization using alkane crystal deposition and viscosity experiments. Strong hydrophobic forces between poly(hexadecyl-grafted aminocrotonate?methacrylic acid) and long-chain hydrocarbon alkane molecules changed the surface properties of the long-chain hydrocarbon alkane nucleus and inhibited the growth of paraffin crystals.
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